Many people like to use alternative Twitter clients, but I find the main Twitter app to be more than sufficient for most of my twitter usage.
I don't create many Vine's myself, but I can waste a great deal of time watching other people get really creative with 6 seconds of video.
The Riposte app is a great App.Net client, a twitter like service.
I use the Google+ app to read posts on Google+. Not much else to say here.
Love it or hate it, Facebook is the only way I communicate with some of my friends. The Facebook app gets the job done.
Restaurant reviews and information. The Yelp app gets better with every update. Why don't more people use it?
I watch an amazing amount of content on YouTube. I often use the YouTube app to stream videos to my Apple TV.
Store your passwords securely. Generate new passwords. Keep the data sync'd across your devices and computers.
Argus and Nike+ Move
The M7 chip in the iPhone 5s made has replaced the Fitbit. Argus and the Nike+ Move app can read the data stored in the M7 and show me that I should be exercising way more than I am.